- Let Me Be Your StarMusic and lyrics by Marc Shaiman and Scott WittmanPerformed by Uma Thurman
- The 20th Century Fox MamboMusic and lyrics by Marc Shaiman and Scott WittmanPerformed by Uma Thurman and the ensemble
- Mr. & Mrs. SmithMusic and lyrics by Marc Shaiman and Scott WittmanPerformed by Uma Thurman and Will Chase
- The National PastimeMusic and lyrics by Marc Shaiman and Scott WittmanPerformed by Uma Thurman and the cast of Bombshell
- Don't Say Yes Until I Finish TalkingMusic and lyrics by Marc Shaiman and Scott WittmanPerformed by Marc Kudisch and the ensemble
- Smash!Music and lyrics by Marc Shaiman and Scott WittmanPerformed by Megan Hilty, Katharine McPhee and the female members of the ensemble
- Second-Hand White Baby GrandMusic and lyrics by Marc Shaiman and Scott WittmanPerformed by Uma Thurman
- September SongMusic by Kurt WeillLyrics by Maxwell AndersonPerformed by Anjelica Huston
- StandWritten by Sly Stone (as Stewart & Sylvester)Performed by Leslie Odom Jr., 'Katharine McPhee' and the members of the gospel choir
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