The program was chapterised into seven segments each beginning with a dictionary definition type introduction. These included:
- Bond women
- Villains ( sub. Villains' lair )
- Locations
- Stunts
- Q
- Music ( sub. Composer )
- and Bond, James Bond.
Included as a special feature on the The World Is Not Enough (1999) disc in the Bond 50 bluray collection, released in 2013.